The
periodic
table of the chemical elements is a tabular display of the known chemical
elements. The elements are arranged by electron structure so that many chemical
properties vary regularly across the table. Each element is listed by its atomic
number and chemical symbol.
The standard table provides the necessary basics.
There are also other methods for displaying the chemical elements for more details
or different perspectives.Standard periodic table
Color coding for atomic numbers:
- Elements numbered
in blue are liquids at standard
temperature and pressure (STP);
- those in green
are gases at STP;
- those in black are solid at STP;
- those in red are synthetic (all are
solid at STP).
- those in gray have not yet been
discovered (they also have muted fill colors indicating the likely chemical series
they would fall under).
Groups
A
group is a vertical
column in the periodic table of the elements. There are 18 groups in the standard
periodic table. Elements in a group have similar configurations of their valence shell electrons,
which gives them similar properties.
Group
numbers
There are three systems of group numbers;
one using Arabic numerals and the other two using Roman numerals. The Roman numeral
names are the original traditional names of the groups; the Arabic numeral names
are a newer naming scheme recommended by International Union of Pure and Applied
Chemistry (IUPAC). The IUPAC scheme was developed to replace both older Roman
numeral systems as they confusingly used the same names to mean different things.
Explanation
of the structure of the periodic table
The number of electron shells an atom
has determines what period it belongs to. Each shell is divided into different
subshells, which as atomic number increases are filled in roughly this order:
1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f 5d 6p 7s 5f 6d 7p 8s 5g 6f 7d 8p ...
Hence the structure of the table. Since the outermost electrons determine chemical
properties, those tend to be similar within groups. Elements adjacent to one another
within a group have similar physical properties, despite their significant differences
in mass. Elements adjacent to one another
within a period have similar mass but different properties.
For example,
very near to nitrogen (N) in the second period
of the chart are carbon (C) and oxygen (O). Despite their similarities
in mass (they differ by only a few atomic mass units), they
have extremely different properties, as can be seen by looking at their allotropes:
diatomic oxygen is a gas that supports burning, diatomic
nitrogen is a gas that does not support burning, and carbon is a solid which can be burnt (yes, diamonds can be
burnt!).
In contrast, very near to chlorine (Cl) in the next-to-last
group in the chart (the halogens) are fluorine (F) and bromine (Br). Despite
their dramatic differences in mass within the group, their allotropes have very
similar properties: They are all highly corrosive (meaning they combine
readily with metals to form metal
halide salts);
chlorine and fluorine are gases, while bromine is a very low-boiling liquid; chlorine and
bromine at least are highly colored.
History
Main
article: History of the
periodic table
The original table was created without a knowledge
of the inner structure of atoms:
if one orders the elements by atomic mass, and then plots
certain other properties against atomic mass, one sees an undulation or periodicity
to these properties as a function of atomic mass. The first to recognize these
regularities was the German chemist Johann Wolfgang
Döbereiner who, in 1829, noticed a number of triads
of similar elements:
| Some
triads |
| Element | Atomic mass | Density |
| chlorine | 35.5 | 0.00156 g/cm3 |
| bromine | 79.9 | 0.00312 g/cm3 |
| iodine | 126.9 | 0.00495
g/cm3 |
|
| calcium | 40.1 | 1.55
g/cm3 |
| strontium | 87.6 | 2.6 g/cm3 |
| barium | 137 | 3.5 g/cm3 |
This
was followed by the English chemist John Alexander
Reina Newlands, who in 1865 noticed that the elements of
similar type recurred at intervals of eight, which he likened to the octaves of music,
though his law of octaves was ridiculed by his contemporaries. Finally,
in 1869, the German
Lothar
Meyer and the Russian chemist Dmitry Ivanovich
Mendeleev almost simultaneously developed the first periodic table, arranging
the elements by mass. However, Mendeleev plotted a few elements out of strict
mass sequence in order to make a better match to the properties of their neighbours
in the table, corrected mistakes in the values of several atomic masses, and predicted
the existence and properties of a few new elements in the empty cells of his table.
Mendeleev was later vindicated by the discovery of the electronic structure of
the elements in the late 19th and early 20th century.
External
links
- "Presentation forms of
the periodic table (http://www.wou.edu/las/physci/ch412/alttable.htm)".
Western Oregon University.
- "A Brief History of the
Development of Periodic Table (http://www.wou.edu/las/physci/ch412/perhist.htm)".
Western Oregon University.
- "Visual Periodic
Table (http://www.chemsoc.org/viselements/pages/periodic_table.html)".
ChemSoc.org.
- Barbalace, Kenneth L., "Biochemical Periodic
Tables (http://environmentalchemistry.com/yogi/periodic/)".
KLBProductions.com.
- "Periodic table (http://www.webelements.com) (professional
edition)". WebElements.
- Counterman, Craig, "Periodic Table of the
Elements : Atomic Number (http://web.mit.edu/3.091/www/pt/)". MIT
Course 3.091.
- Holler, F. James, and John P. Selegue, "Periodic Table of Comic Books
(http://www.uky.edu/Projects/Chemcomics/)".
Department of Chemistry, University of Kentucky. 1996-2002.
- Heilman, Chris,
"The Pictorial Periodic
Table (http://chemlab.pc.maricopa.edu/periodic/default.html)".
(Includes alternate styles: Stowe, Benfey, Zmaczynski, Giguere, Tarantola, Filling,
Mendeleev)
- "Periodic table (http://pearl1.lanl.gov/periodic/default.htm)".
Los Alamos National Laboratory's Chemistry Division.
- "Periodic Table
of the Fermi Surfaces of Elemental Solids (http://www.phys.ufl.edu/fermisurface/periodic_table.html)".
The Fermi Surface Database
(http://www.phys.ufl.edu/fermisurface/)
- "Interactive NMR Frequency
Map (http://www.nyu.edu/cgi-bin/cgiwrap/aj39/NMRmap.cgi)".
Texas A&M.
- "Periodic Table Elements (http://www.science.co.il/PTelements.asp)".
Israel Science and Technology Directory. 1999-2004. (sorted by physical characteristics)
- Barthelmy, David, "Periodic table (http://webmineral.com/chemical.shtml)"
Mineralogy Database. (mineral emphasis)
- Gray, Theodore, "Wooden Periodic Table Table
(http://www.theodoregray.com/PeriodicTable/)"
(with samples)
- "Periodic
table applet (http://www.dartmouth.edu/~chemlab/info/resources/p_table/Periodic.html)".
Dartmouth College. (Java)
- Jacobs,
Bob, "Periodic Tables
(http://www.chemistrycoach.com/periodic_tables.htm)
(in case you were thinking that the Internet needed one more)". The Chemistry
Coach.
- "Periodic Table (http://periodictable.com/).Com".